174

De Broglie Wavelength

In 1923 a French physics graduate student named Prince Louis-Victor de Broglie (1892–1987) made a radical proposal based on the hope that nature is symmetric. If EM radiation has both particle and wave properties, then nature would be symmetric if matter also had both particle and wave properties. If what we once thought of as an unequivocal wave (EM radiation) is also a particle, then what we think of as an unequivocal particle (matter) may also be a wave. De Broglie’s suggestion, made as part of his doctoral thesis, was so radical that it was greeted with some skepticism. A copy of his thesis was sent to Einstein, who said it was not only probably correct, but that it might be of fundamental importance. With the support of Einstein and a few other prominent physicists, de Broglie was awarded his doctorate.

De Broglie took both relativity and quantum mechanics into account to develop the proposal that all particles have a wavelength, given by

where \(h\) is Planck’s constant and \(p\) is momentum. This is defined to be the de Broglie wavelength. (Note that we already have this for photons, from the equation \(p=h/\lambda \).) The hallmark of a wave is interference. If matter is a wave, then it must exhibit constructive and destructive interference. Why isn’t this ordinarily observed? The answer is that in order to see significant interference effects, a wave must interact with an object about the same size as its wavelength. Since \(h\) is very small, \(\lambda \) is also small, especially for macroscopic objects. A 3-kg bowling ball moving at 10 m/s, for example, has

This means that to see its wave characteristics, the bowling ball would have to interact with something about \({\text{10}}^{\text{–35}}\phantom{\rule{0.25em}{0ex}}\text{m}\) in size—far smaller than anything known. When waves interact with objects much larger than their wavelength, they show negligible interference effects and move in straight lines (such as light rays in geometric optics). To get easily observed interference effects from particles of matter, the longest wavelength and hence smallest mass possible would be useful. Therefore, this effect was first observed with electrons.

American physicists Clinton J. Davisson and Lester H. Germer in 1925 and, independently, British physicist G. P. Thomson (son of J. J. Thomson, discoverer of the electron) in 1926 scattered electrons from crystals and found diffraction patterns. These patterns are exactly consistent with interference of electrons having the de Broglie wavelength and are somewhat analogous to light interacting with a diffraction grating. (See (Figure).)

De Broglie’s proposal of a wave nature for all particles initiated a remarkably productive era in which the foundations for quantum mechanics were laid. In 1926, the Austrian physicist Erwin Schrödinger (1887–1961) published four papers in which the wave nature of particles was treated explicitly with wave equations. At the same time, many others began important work. Among them was German physicist Werner Heisenberg (1901–1976) who, among many other contributions to quantum mechanics, formulated a mathematical treatment of the wave nature of matter that used matrices rather than wave equations. We will deal with some specifics in later sections, but it is worth noting that de Broglie’s work was a watershed for the development of quantum mechanics. De Broglie was awarded the Nobel Prize in 1929 for his vision, as were Davisson and G. P. Thomson in 1937 for their experimental verification of de Broglie’s hypothesis.

Electron Microscopes

One consequence or use of the wave nature of matter is found in the electron microscope. As we have discussed, there is a limit to the detail observed with any probe having a wavelength. Resolution, or observable detail, is limited to about one wavelength. Since a potential of only 54 V can produce electrons with sub-nanometer wavelengths, it is easy to get electrons with much smaller wavelengths than those of visible light (hundreds of nanometers). Electron microscopes can, thus, be constructed to detect much smaller details than optical microscopes. (See (Figure).)

There are basically two types of electron microscopes. The transmission electron microscope (TEM) accelerates electrons that are emitted from a hot filament (the cathode). The beam is broadened and then passes through the sample. A magnetic lens focuses the beam image onto a fluorescent screen, a photographic plate, or (most probably) a CCD (light sensitive camera), from which it is transferred to a computer. The TEM is similar to the optical microscope, but it requires a thin sample examined in a vacuum. However it can resolve details as small as 0.1 nm (\({\text{10}}^{-\text{10}}\phantom{\rule{0.25em}{0ex}}m\)), providing magnifications of 100 million times the size of the original object. The TEM has allowed us to see individual atoms and structure of cell nuclei.

The scanning electron microscope (SEM) provides images by using secondary electrons produced by the primary beam interacting with the surface of the sample (see (Figure)). The SEM also uses magnetic lenses to focus the beam onto the sample. However, it moves the beam around electrically to “scan” the sample in the x and y directions. A CCD detector is used to process the data for each electron position, producing images like the one at the beginning of this chapter. The SEM has the advantage of not requiring a thin sample and of providing a 3-D view. However, its resolution is about ten times less than a TEM.

Electrons were the first particles with mass to be directly confirmed to have the wavelength proposed by de Broglie. Subsequently, protons, helium nuclei, neutrons, and many others have been observed to exhibit interference when they interact with objects having sizes similar to their de Broglie wavelength. The de Broglie wavelength for massless particles was well established in the 1920s for photons, and it has since been observed that all massless particles have a de Broglie wavelength \(\lambda =h/p.\) The wave nature of all particles is a universal characteristic of nature. We shall see in following sections that implications of the de Broglie wavelength include the quantization of energy in atoms and molecules, and an alteration of our basic view of nature on the microscopic scale. The next section, for example, shows that there are limits to the precision with which we may make predictions, regardless of how hard we try. There are even limits to the precision with which we may measure an object’s location or energy.